Synthesis and characterization of novel metal-organic frameworks for gas adsorption applications

Thesis Abstract

Abstract
Metal-organic frameworks (MOFs) have emerged as promising materials for gas adsorption applications due to their high surface area, tunable pore size, and chemical versatility. This thesis focuses on the synthesis and characterization of novel MOFs tailored specifically for gas adsorption purposes. The research involved the design and synthesis of MOFs using different metal nodes and organic linkers to achieve optimal gas adsorption properties. Characterization techniques such as X-ray diffraction, scanning electron microscopy, and gas adsorption measurements were employed to analyze the structural and adsorption properties of the synthesized MOFs. The literature review provides a comprehensive overview of the current state of MOF research, emphasizing the importance of MOFs in gas storage, separation, and catalysis applications. It also discusses the key factors influencing gas adsorption in MOFs, including pore size, surface area, and functional groups. The research methodology section details the experimental procedures used for the synthesis of MOFs, including the choice of metal nodes and organic linkers, reaction conditions, and characterization techniques. The chapter also outlines the methods for measuring gas adsorption isotherms and evaluating the adsorption performance of the synthesized MOFs. The results and discussion chapter presents the findings of the study, including the structural properties, gas adsorption capacities, and selectivity of the synthesized MOFs. The effects of different metal nodes and organic linkers on the gas adsorption properties of the MOFs are discussed in detail, highlighting the importance of structural design in optimizing gas adsorption performance. In conclusion, this thesis demonstrates the successful synthesis and characterization of novel MOFs tailored for gas adsorption applications. The research findings provide valuable insights into the design principles for developing MOFs with enhanced gas adsorption properties. The significance of this work lies in the potential application of these novel MOFs in gas storage, separation, and catalysis, contributing to the advancement of sustainable energy and environmental technologies.