Sintering characteristics of itakpe and agbaja iron ore concentrates blends
Table Of Contents
- TITLE PAGE ……………………………………………………………………………………………… i
DECLARATION ………………………………………………………………… ii
CERTIFICATION ……………………………………………………………… iii
DEDICATION ………………………………………………………………….. iv
ACKNOWLEDGEMENT ……………………………………………………. v
ABSTRACT ……………………………………………………………………… vi
TABLE OF CONTENTS …………………………………………………… vii
LIST OF TABLES …………………………………………………………….. xi
LIST OF FIGURES …………………………………………………………. xiiii
LIST OF APPENDIX ……………………………………………………….. xiii
NOTATIONS ………………………………………………………………….. xiv
Chapter ONE
INTRODUCTION
- …………………………………………………………………. 1
- 1.0INTRODUCTION ………………………………………………………………….. 1
- 1.1Statement of problem ……………………………………………………………… 4
- 1.2Aims and Objectives of the Study ……………………………………………… 5
- 1.3Justification and Significance of the study ………………………………….. 5
- 1.4Limitations of the research ……………………………………………………….. 6
viii
Chapter TWO
LITERATURE REVIEW
- ………………………………………………………………… 7
- 2.0LITERATURE REVIEW ………………………………………………………… 7
- 2.1INTRODUCTION ………………………………………………………………….. 7
- 2.2Nigerian Iron Ore Deposits ………………………………………………………. 7
- 2.3Agbaja Iron Ore Deposit. Reserve and Chemical compositions ……… 9
2.
- 3.1Chemical Composition of Agbaja Iron Ore ……………………………………………… 9
2.
- 3.2Itakpe Iron Ore Deposit, Reserve and Chemical Analysis …………………………. 10
2.
- 3.3Chemistry and Mineralogy of Itakpe Iron Ore ………………………………………… 11
- 2.4Fluxes ……………………………………………………………………………………11
2.
- 4.1Basic fluxes ……………………………………………………………………………………… 12
2.
- 4.2Aluminous Fluxes …………………………………………………………………………….. 12
2.
- 4.3Acid fluxes………………………………………………………………………………………. 12
- 2.5Definition and Concept of Sintering …………………………………………..13
- 2.6Background of Sintering ………………………………………………………….14
- 2.7Reduction Reactions that occurred During Sintering …………………….16
- 2.8Process Variables during Sintering …………………………………………….17
2.
- 8.1Roles of sinter returns in sintering ………………………………………………………… 18
2.
- 8.2Positive effect of sinter return on gas permeability ………………………………….. 18
- 2.9Types of Sinters …………………………………………………………………….18
- 2.10Desired Qualities of sinters ……………………………………………………19
- 2.11Comparison between sinters and pellets ………………………………….21
ix
- 2.12Charge Calculations for sinter production ………………………………..22
- 2.13Mechanisms and Kinetics of reduction of blast furnace burden …..23
Chapter THREE
SYSTEM DESIGN AND IMPLEMENTATION
- …………………………………………………………… 30
- 3.0EXPERIMENTAL TECHNIQUES …………………………………………..30
- 3.1MATERIALS ………………………………………………………………………..30
- 3.2Methods …………………………………………………………………………………31
3.
- 2.1Charge calculation …………………………………………………………………………….. 31
3.
- 2.2Determination of Abrasion Index Value (AIV) ……………………………………….. 33
3.
- 2.3Determination of Shatter Index Value (SIV) ………………………………………….. 34
3.
- 2.4Determination of Tumbler Index Value (TIV) ………………………………………… 34
3.
- 2.5Determination of Reducibility Index Value (RIV) …………………………………… 34
3.
- 2.6Determination of Reduction Decrepitation Index Value (RDIV)………………… 35
3.
- 2.7Determination of Chemical Composition of Sinters …………………………………. 35
3.
- 2.8Determination of Phosphorous content of the blends by calculation …………… 35
Chapter FOUR
SYSTEM TESTING AND EVALUATION
- …………………………………………………………….. 38
- 4.0RESULTS AND DISCUSSION ……………………………………………….38
- 4.1Results ………………………………………………………………………………….38
4.
- 2.0Discussion ……………………………………………………………………………..42
4.
- 2.1Abrasion Index Values (AIV)…………………………………………………………….. 42
4.
- 2.2Shatter Index Values (SIV) …………………………………………………………………. 43
4.
- 2.3Tumbler Index Values (TIV) ……………………………………………………………….. 44
x
4.
- 2.4Reducibility Index Values (RIV) ………………………………………………………….. 45
4.
- 2.5Reduction Decrepitation Index Values (RDIV) ………………………………………. 46
4.
- 2.6Chemical Analysis of Sinters ………………………………………………………………. 47
Chapter FIVE
SUMMARY, CONCLUSION AND RECOMMENDATIONS
- ………………………………………………………………. 48
Chapter FIVE
SUMMARY, CONCLUSION AND RECOMMENDATIONS
- ………………………………………………………………. 49
- 5.0CONCLUSION AND RECOMMENDATION ……………………………49
- 5.1CONCLUSION ……………………………………………………………………..49
- 5.2RECOMMENDATIONS …………………………………………………………49
REFERENCES …………………………………………………………………. 51
Thesis Abstract
This research investigated the sintering characteristics of sinter blends produced from
Agbaja iron ore concentrate of high phosphorus (P2O5 = 1.50 – 2.14%) and low silica
content and Itakpe iron ore concentrate of low phosphorus (P = 0.03%) and high silica in
order to produce fluxed sinters suitable for pig iron production. The ores (Agbaja and
Itakpe) were concentrated using conventional beneficiation techniques and then blended
in the ratios of 10-70% Agbaja and 90-30% Itakpe. The blends were mixed with coke
breeze, limestone and moisture to produce fluxed sinters. The physical and chemical
characteristics of the produced sinters vis-a-visa abrasion resistance, shatter index,
tumbler index, reducibility, reduction decrepitating and chemical composition were
determined. The results obtained revealed that both the physical and chemical properties
of the produced sinters compared favourably with existing blast furnace specifications for
sinters. However, the sinter with 10% Agbaja and 90% Itakpe possessed physical and
chemical properties that are close to the specified properties of sinter for use in the blast
furnace for Pig iron production. Therefore, sinter blend with 10% Agbaja and 90%
Itakpe iron concentrates can be recommended for use in blast furnace for the production
of pig iron.
Thesis Overview
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1.0 INTRODUCTION<br>In order to ensure the survival of any industry, raw materials input must be critical and<br>continuously be in supply both in large quantity and in good quality. Even though Nigeria<br>is blessed with large quantity of iron ore deposit of about three billions (3 x 109) metric<br>tonnes, these deposit cannot be used directly in pig iron production without beneficiation<br>because some of them are of low grade and contain impurities, which can be detrimental<br>to the properties of the steels to be produced. Some researches have already been carried<br>out on the beneficiation of some of these ores for use for pig iron production by, Adigwe<br>(1973), and Oloche et al., (1996).<br>Eventhough Nigeria is blessed with large reserves of proven and unproven iron ore<br>deposits, only one of the deposits in the proven reserves is currently being exploited and<br>processed that is the Itakpe iron ore deposit. This deposit has an estimated reserve of<br>about 200 millions (200 x 106) metric tonnes and has been earmarked to be supplied to<br>Ajaokuta and Delta steel plants. However, this deposit, based on the designed<br>requirement of the Ajaokuta plant, will only last for 25 years (Adigwe, 1983). This is<br>grossly inadequate for the establishment of a formidable foundation for a well- projected<br>and integrated iron and steel plants. Also the Agbaja iron ore deposit, eventhough the<br>largest iron ore deposit in Nigeria estimated at over 2 billions (2 x 109) metric tonnes, has<br>a very high phosphorous content in addition to its extremely fine grained texture. This<br>feature has discouraged its utilization to date (BRGM Report, 1983). With these apparent<br>problems it has become very necessary to find ways of using this vast deposit of iron ore.<br>2<br>The most probable way to utilize the large quantity of iron ore is by blending with other<br>iron ores with lower phosphorous content. Therefore, the objective of this work is to<br>blend Itakpe super concentrate of low phosphorous with the Agbaja concentrate of high<br>phosphorus so as to produce a sinter mix that can serve as feed to blast furnace for pig<br>iron production.<br>Kurt (1980) said that both sinters and pellets are used as feed with iron but sinters are the<br>common and suitable sources of feeds to the blast furnace. The process of sintering<br>comprises high temperature-treatment (above 10000C) of iron fines on a moving grate,<br>blended with fluxes and coke breeze (finely divided coke) to form hard lumps or iron-rich<br>material suitable for use as blast furnace feed (Williams, 1983). In iron ore sintering, the<br>aim is always to produce a strong but porous agglomerate from a sandy uncompacted<br>mass. Tupkary et al., (1998) also noted that in order to obtain smooth and hard “rapid<br>driving operation”, the burden charged in the furnace should ideally posses the following<br>physical and chemical properties.<br>Physical properties<br>1. A close size range with minimum of fines.<br>2. An ability to withstand the physical stresses incurred on being transported to<br>the furnace, charged to the hopper and the bells and, finally in the furnace.<br>3. Non –decrepitating nature.<br>4. An ability to withstand mild reducing condition at lower temperature without<br>breaking.<br>3<br>5. A good bulk reducibility so as to obtain closed equilibrium conditions<br>between solid and gas phases in the stack.<br>6. Low swelling tendency during reduction.<br>7. A high softening temperature with a narrow temperature range of fusion.<br>Chemical properties<br>1. A high percentage of iron to gangue ratio.<br>2. A low percentage of silica, alumina and a low alumina to silica ratio.<br>3. Good overall chemistry of the burden to ensure adequate desulphurization of<br>metal and absorption of coke ash in slag.<br>4. Good overall chemistry to ensure clean slag and metal separation at minimum<br>temperature and free flow of both slag and metal.<br>In addition, sintering is also carried out to improve size grading and reducibility of iron<br>ore concentrate to avoid wasting of fines, reduction of the quantity of coke used in the<br>blast furnace and lastly to use up waste materials from blast furnace flue dust.<br>The quantity of sinter produced by the integrated blast furnace route has risen from<br>371.2mt in1982 to 422.7mt in 1994, accounting for 55.0% to 57.9% of total crude steel<br>production. Therefore more than 50% of the total liquid iron production during this<br>period was supplied via the blast furnace for which sinters remain the major iron feed<br>stock. However, Pellets are gradually replacing sinters to a certain degree, depending on<br>available local process, economic and environmental circumstances with the global<br>4<br>output of the two products in 1994 standing at 534.3mt and 224.7mt for sinter and pellet<br>respectively (Madugu, 2001).<br>Iron ore sintering is a complex thermo-chemical process and the qualities of sinters being<br>produced affect the blast furnace performances in terms of fuel consumption, smooth<br>operation, and rate of production. (Nath et al., 2004). Presently, the proportion of sinters<br>in the charge of most blast furnaces amounts to 90% of the total weight of charge.<br>Recently, the use of sinters is gradually increasing as mines produce more dusty,<br>complex and lean ores, which need to be ground to a very fine particle before<br>beneficiation. The world trend for use of sinters in pig iron production via the<br>conventional blast furnace (acid and basic) is given in Appendix 1.0. Ogg et al., (1977)<br>observes that the production and use of sinter for pig iron and hot metal manufacture<br>continues to grow in 90% of the world’s steelmaking areas. This expansion is often faster<br>than the growth of iron production, showing that the use of sinter in the blast furnace will<br>continue to increase since the iron content of the ores to be sinter is generally rising and<br>thereby lower the slag volume in the blast furnace.<br>1.1 Statement of problem<br>Agbaja ore deposit has an estimated reserve of about 2 billions (2 x 109) metric tonnes,<br>containing high phosphorus (P2O5 = 1.5-2.14%) and low silica, because of this, the<br>deposit is not suitable for pig iron production. Phosphorus exists in iron ores as<br>phosphorus pentoxide (P2O5) and this cannot be reduced during beneficiation technique<br>and agglomeration. Kudrin (1989) observes that the effects of the phosphorus on the<br>machined iron properties and steel are enormous. In order to use Agbaja iron ore, it is<br>5<br>imperative to blend the ore with Itakpe iron ore with a reserve of about 200-300 million<br>metric tonnes having low phosphorus (0.03%) and high silica to take care of the high<br>phosphorus in Agbaja iron ore and also to provide large source of iron ore for sinter<br>production.<br>1.2 Aims and Objectives of the Study<br>The main aim is to determine the optimum-blending ratio, the ratio at which the two ores,<br>when blended will produce sinters with physical and chemical properties that are suitable<br>for pig iron production via the blast furnace process. The results obtained will also be<br>compared with the minimum standard specifications required of sinters for pig iron<br>production via the blast furnace route.<br>1.3 Justification and Significance of the study<br>The Agbaja iron ore deposit exists in large quantity and it is very close to Ajaokuta.<br>Because of high phosphorus associated with it, there is the need to intensify effort in<br>order to find the means of utilizing the ore economically. One of such means/alternatives<br>is by blending which is the main focus of this research work.<br>If this research is successful, it will find a solution to the use of Agbaja through blending<br>with Itakpe iron ore for the production of sinters for Ajaokuta Steel Company. This will<br>augment the source of raw material input for pig iron production at Ajaokuta Steel<br>Company. Also the sinter to be produced could be exported as this will attract foreign<br>exchange earning.<br>6<br>1.4 Limitations of the research<br>As a result of non-availability of some equipment, certain tests, like swelling index, hot<br>compression strength and low temperature characteristics may not be carried out.
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