Production and weld joint performance evaluation of arc welding electrodes from dana rolling mill scales
Table Of Contents
- Cover Page i
Title Page ii
Declaration iii
Certification iv
Dedication v
Acknowledgement vi
Table of Contents vii
List of Tables xi
List of Figures xii
List of Plates xiii
Abstract xv
Chapter ONE
INTRODUCTION
- 1.0INTRODUCTION 1
- 1.1Overview of Welding 1
1.
- 1.1Types of welding 2
1.
- 1.2Types of arc welding 3
1.
- 1.3Development of welding 5
- 1.2Statement of Problem 6
- 1.3Present Research 7
- 1.4Aim and Objectives 8
- 1.5Justification 8
8
Contents Pages
- 1.6Research Scope 9
Chapter TWO
LITERATURE REVIEW
- 2.0LITERATURE REVIEW 10
- 2.1Electrode Overview 10
- 2.2Types of Arc Welding Electrodes 12
2.
- 2.1Consumable electrode s 12
2.
- 2.2Non consumable electrodes 12
- 2.3Classification of Electrode Coatings 12
2.
- 3.1Gas forming component 13
2.
- 3.2Slag forming component 13
2.
- 3.3Reducing component 13
2.
- 3.4Stabilizing component 13
2.
- 3.5Binding component 13
- 2.4Types of electrode coatings 13
2.
- 4.1Gas shielded (cellulosic) electrodes 14
2.
- 4.2Rutile electrodes 14
2.
- 4.3Iron oxide electrodes 14
2.
- 4.4Basic electrodes 14
- 2.5Review of Related Researches 14
9
Chapter THREE
SYSTEM DESIGN AND IMPLEMENTATION
- 3.0MATERIALS AND METHODS 22
Contents Pages
- 3.1Introduction 22
- 3.2Materials 22
- 3.3Equipment 25
- 3.4Experimental Procedure 26
3.
- 4.1Chemical composition formulation process 28
3.
- 4.2Production process 34
3.
- 4.3Mechanical tests 36
3.
- 4.4Production cost determination 37
3.
- 4.5Estimated cost for the produced electrodes 37
- 3.5Sample Preparation 39
3.
- 5.1Tensile test samples 39
3.
- 5.2Hardness test samples 41
3.
- 5.3Impact test samples 42
3.
- 5.4Metallographic examination 42
Chapter FOUR
SYSTEM TESTING AND EVALUATION
- 4.0RESULTS 45
- 4.1Introduction 45
- 4.2Results of Mechanical Tests Conducted 45
10
Chapter FIVE
SUMMARY, CONCLUSION AND RECOMMENDATIONS
- 5.0DISCUSSION OF RESULTS 53
- 5.1Elemental Analysis of Mill Scales 53
- 5.2Performance Evaluation of Welded Joints 53
Contents Pages
- 5.3Micrographs of Weldments and Heat Affected Zone 56
CHAPTER SIX
- 6.0CONCLUSION AND RECOMMENDATIONS 58
- 6.1Conclusion 58
- 6.2Recommendations 59
References 60
Appendices 64
11
Thesis Abstract
This study explored the possibility of producing Iron Oxide based arc welding electrodes
using mill scales from Dana rolling mill. The performance of the weld joints using the
produced electrodes and a foreign electrode was also examined. It is estimated that 4000-5000
tons of mill scales are produced annually without any immediate industrial application. The
mill scales were collected prepared and analyzed using the Oxford 800 X Supreme XRF
machine. The report of the analysis shows the presence of predominantly Iron Oxide, which is
an important constituent in electrode coating. The flux compositions were generated using the
Hadamard multivariate chemical model. Using this model, twelve different flux compositions
emerged within given ranges of the constituent flux elements. Four of the flux compositions
were used to produce electrodes using sodium silicate as binder. The electrodes were produced
manually by means of a wooden mould. The produced electrodes (E6020, E6027, E6024 and
E6030) and a foreign electrode were used to carry out weld on some prepared samples. The
welded joints were tested for tensile, hardness, and impact tests. The results of the tests
conducted on all the welded joints using the produced electrodes and the foreign electrode
shows that all the produced electrodes with the exception of electrode type E6030 compete
well with the foreign electrode (Oerlikon). Electrode type E6020 gave the highest tensile and
hardness test results of 453N/mm2 and 457.1N respectively. The maximum impact energy was
found to be 94.9 joules on the sample welded with the electrode type E6030. The micrographs
of the weld joint using electrode type E6027 revealed a coarse pearlite (black matrix) and an
elongated ferrite (white matrix). To this end, this study established the need to maximize the
use of mill scales (an industrial waste) for the production of arc welding electrodes and by so
doing conversion of waste to worth would have been achieved.
Thesis Overview
<p>
1.0 INTRODUCTION<br>1.1 Overview of Welding<br>Welding is a production or a fabrication process of joining two or more materials<br>together, usually metals or thermoplastics to achieve coalescence. Welding is performed by<br>the application of heat and pressure to melt the work piece together often with the addition of<br>filler material to form a pool of molten material which form the welded joint after<br>solidification (<a target="_blank" rel="nofollow" href="http://www.metal_processing/welding.cfm)">www.metal_processing/welding.cfm)</a>. Many welding processes are<br>accomplished by heat alone, with no pressure applied; others by a combination of heat and<br>pressure; and still others by pressure alone, with no external heat applied.<br>Welding processes are used to produce joints with properties similar to those of<br>materials being joined, these materials are called parent materials.Welding process usually<br>involves raising the materials at the joint to elevated temperature (Ibhadode, 2001). There are<br>three main components to create a weld and these components are:<br>1 A heat source: A heat source is an important component in the creation of weld, a<br>heat source include an electric arc, a flame, pressure or friction. However, the most<br>common heat source is the electric arc.<br>2 Shielding: Shielding is the use of gas or another substance to protect the weld from<br>atmospheric contamination of the molten weld.<br>3 Filler material: They are used in joining two pieces of materials together, usually<br>metals.<br>Welding is extensively used in fabrication and has found application as an alternative method<br>for casting or forging and as a replacement for bolted and riveted joints. It is also used as a<br>repair medium, for example to reunite metals at a crack, to build up a small part that has<br>17<br>broken off, such as gear tooth or to repair a worn surface such as a bearing surface(Khurmi<br>and Gupta, 2005).<br>The objective of welding is to join pieces of metals together by means of suitable<br>heatsource(Lancaster, 1993).Advantages of welding as a joining process include high joint<br>efficiency, simple set up, flexibility and low fabrication cost (Armentani et al., 2007).<br>Today, many process of welding have been developed and probably there is no industry which<br>is not using welding process in the fabrication of its product in one form or other, hence<br>welding process can be broadly classified, as fusion welding and solid phase welding.<br>1.1.1 Types of welding<br>Fusion welding: This type of welding operation involves joining two pieces of metals together<br>by the application of heat. The two materials or parts to be joined are placed together and<br>heated, often with the addition of filler metal, until they melt and solidify on cooling. Types of<br>fusion welding include electric arc welding, electrical resistance welding, gas welding etc.<br>Solid phase welding: This type of welding operation is achieved by bringing the clean faces of<br>the materials to be joined into intimate contact to produce a metallic bond. Solid phase<br>welding can be performed with or without the application of heat. However pressure<br>application is important so as to induce plastic flow (Jain, 2008). Heat or temperature<br>distribution that occurs during welding greatly affects the microstructure of the weld, and<br>hence the weld properties (Kou, 2003). At the end of a welding operation, the complete weld<br>metal and metal pieces having been joined should now to all intents, be one piece of metal<br>(Somksy, 1986).<br>After welding, a number of distinct regions are identified in the weld area, the weld<br>itself is called the fusion zone, and it is a portion where the filler metal was laid during the<br>welding process. The property of the fusion zone is dependent on the filler metal used and its<br>18<br>compatibility with the base materials, the fusion zone is surrounded by the heat affected zone.<br>The heat affected zone is the area that had its microstructure and properties altered as a result<br>of heat during welding. The fusion zone and the heat affected zone microstructure properties<br>depend on the base materials behavior when subjected to heat(Cary and Helzer, 2005). The<br>properties and microstructure of heat affected zone depends on the rate of heat input and<br>cooling and also the temperature at which the zone is raised during welding (Kalpakjian and<br>Schmid, 2006).<br>Arc welding is one of the several fusion processes of joining metals. By the application<br>of intense heat, metal at the joint between two parts are melted and caused to intermix directly<br>or, more commonly with an intermediate molten filler metal, which when solidify a<br>metallurgical bond results which is called weldment. In arc welding, the intense heat needed to<br>melt the metal is produced by an electric arc, and the electric arc is formed between the work<br>pieces to be welded and an electrode that is manually or mechanically moved along the joint<br>(Hwaiyu, 2004). An electric arc is obtained when an electric current flows between two<br>electrodes separated by a short distance, in electric arc welding, one electrode is the welding<br>rod and the other is the work piece being welded (Ibhadode, 2001).<br>1.1.2 Types of arc welding<br>ï‚· Shielded metal arc welding: Shielded metal arc welding is one of the oldest arc<br>welding processes. It is also the simplest and perhaps the most versatile arc welding process<br>used for welding ferrous based metals, because of its flexibility, simplicity and accessibility to<br>difficult locations (Ibhadode, 2001). Shielded metal arc welding process was invented in 1907<br>and is still being widely used today (Kay et al., 2010). It is a manual arc welding process using<br>coated electrodes. Since the electrodes melt and join the work piece, shielded arc welding is<br>classed under consumable arc welding method. The coating on the electrode burns along with<br>the core wire and produces a dense smoke which covers or shield the weld pool and thus<br>19<br>prevent oxidation and absorption of nitrogen by the metal, and this type welding process is<br>used for steel fabrication. Fig 1.1 shows a shielded metal arc welding process with a<br>consumable electrode that melts and produce gaseous shield which prevent oxidation of the<br>molten weld metal.<br>Fig;1.1: Shielded metal arc welding ( Source; Parking and Flood, 1974).<br>ï‚· Submerged arc welding: This is an automatic process developed primarily for the<br>production of high quality butt welds in thicker steel plates. Submerged arc welding is<br>different from other arc welding processes in a way that a blanket of fusible, granular material<br>(flux) which consists of lime, silica, manganese oxide, calcium fluoride and other compounds<br>is used for shielding the arc and the molten metal. The process provides very high deposition<br>rate and a deep penetration and it is used for welding pressure vessels and high pressure pipes.<br>ï‚· Gas tungsten arc welding: Inert gases are used to keep contaminants away from<br>contacting the metal. Gas tungsten arc welding is faster, produces cleaner welds and can weld<br>metals considered to be difficult or impossible to weld, it uses a non-consumable electrode and<br>is used for welding stainless and light gauge materials. The equipment needed for gas tungsten<br>arc welding are welding torch, welding power source and a source of inert gas.<br>ï‚· Gas metal arc welding: This welding operation is performed using direct current<br>reverse polarity as it gives both good cleaning action and fast filler metal deposition rate. Gas<br>20<br>metal arc welding electrode uses a consumable electrode which is fed through the electrode<br>holder in to the arc and at the same speed the electrode is melted and deposited in the weld.<br>ï‚· Plasma arc welding: Plasma is defined as a gas heated to at least practically ionized<br>condition, enabling it to conduct an electric current. Plasma arc refers to a constricted electric<br>arc which is achieved by passing through the water cooled orifice. Plasma arc is made to pass<br>through a small hole in a nozzle which surrounds a non-consumable electrode. This type of<br>welding process has a small heat affected zone and has high welding speed. It is used for<br>welding stainless steel, nickel alloys, refractory and metals in aerospace.<br>ï‚· Electron beam welding: In this process the metal to be joined are brought rather close<br>together and a concentrated stream of high energy electron emitted from a high voltage<br>(150kv) electrode gun is directed on to the surface of the work piece, causing fusion to take<br>place. This welding process is usually performed in the vacuum and thus no flux is required,<br>as there is no air present to contaminate the weld metal. Electron beam welding find<br>application in aerospace and automotive industries.<br>1.1.3 Development of welding<br>Welding as we know it today was not invented until the late 19th century. The earliest<br>form of welding was the forge welding. Forge welding was used by blacksmiths to join metals<br>by heating and pounding until bonding occurred. During the late 1800s gas welding, arc<br>welding with carbon and resistance welding were developed. The advances in welding<br>continued with the invention of metal electrodes which provided a more stable arc in the year<br>1900s.<br>World War1 brought a tremendous demand for a reliable and also an inexpensive<br>joining method throughout the United States. Many companies sprang up in America and<br>Europe to manufacture welding machines to meet the requirement, its first important use was<br>in making repairs for many equipment being chiefly as a repair and maintenance tool, arc<br>21<br>welding has gradually expanded until it now constitutes an important method of fabrication in<br>practically every industry that uses metal. Immediately after the war the America welding<br>society was established to promote welding and other type of allied processes. During the<br>1900s automatic welding was introduced and various types of welding electrodes were<br>developed. Between the year 1920 and 1960, there had been a huge breakthrough in welding<br>with the development of several welding techniques, such as shielded manual arc welding,<br>stud welding, gas tungsten arc welding, electro slag welding, plasma arc welding etc. Most<br>recent was the development of friction stir welding, electron beam welding, laser beam<br>welding and electromagnetic pulse welding (Cary, 1998).<br>Welding has found application in the fabrication of different components, such as<br>pressure vessels, boilers, storage tanks, turbines etc. Today, welding is used in ship building,<br>construction of bridges, and joining automobile parts.<br>1.2 Statement of Problem<br>Examination of mill scales from Dana steel rolling mill in Nigeria, using the Oxford<br>800 X supreme X-ray florescence machine shows the presence of predominantly Iron Oxide<br>(Fe2O3) which constitute more than eighty percent of the total constituent elements of mill<br>scales and which is one of the most important constituents of covering on mild steel arc<br>welding electrodes, serving primarily as slag formers. It is estimated that 4000-5000 tons of<br>mill scales are produced annually with no immediate industrial application (Folayan et al.,<br>1992). Hence mill scales are relatively available and cheap compared to other type of slag<br>formers like titanium oxide (Ti02). As a result of the utilization of these waste (mill scales)<br>there will be actually little cost attached to the main raw material for the production of the<br>electrodes, hence the unit cost of the electrodes to be produced will be affordable. Moreover<br>the diffusible hydrogen content of weld created by rutile electrodes and most especially the<br>cellulosic (foreign) type of electrode is always high, hence the danger of hydrogen<br>22<br>embrittlement of base metal is imminent and there is great possibility of inducing hydrogen<br>cracking in the weld, as the presence of hydrogen in the weld can lead to the creation of<br>hydrogen porosity, which reduces its ductility, strength, and fatigue resistance. Hydrogen can<br>diffuse out of the iron lattice when in solid state resulting in lowering of the mechanical<br>properties of the weld and increasing the tendency to cracking. Therefore use of mill scales as<br>main constituent in the production of Iron oxide based arc welding electrodes prevents the<br>presence of hydrogen build up and its negative consequences. Plate I shows the picture of the<br>Oxford 800 X Supreme XRF machine used for the elemental analysis of mill scales.<br>Plate I: Oxford 800 X supreme XRF machine (Chemistry department ABU, Zaria).<br>1.3 Present Research<br>The importation of electrodes has over the years undermined our efforts in the search<br>for local materials for the production of arc welding electrodes, perhaps due to the belief that<br>the materials for the production of arc welding electrodes locally are not available in Nigeria.<br>Therefore, this research has been conducted to investigate the feasibility of the production of<br>arc welding electrodes using mill scales from Dana rolling mill, and to evaluate the<br>performance of welded joint using the produced electrodes and a foreign electrode. The mill<br>scales was collected and analyzed to determine the percentage composition of Iron oxide<br>present in it. The produced electrodes using mill scales and other materials were used to make<br>23<br>welds on different samples of mild steel and the mechanical properties such as tensile strength,<br>hardness, impact and the metallographic examination of these weldments using the produced<br>electrodes were obtained and compared with welded joints using the foreign electrode.<br>1.4 Aim and Objectives<br>This research work is aimed at utilizing mill scales from Dana steel rolling mill for the<br>production of arc welding electrodes and to evaluate and compare the performance of welded<br>joints using the produced electrodes and a foreign electrode.<br>The specific objectives are:<br>1. To obtain mill scales from Dana steel rolling mill, prepare and analyze the mill scales,<br>to determine the constituent elements.<br>2. To formulate a new flux composition for the electrodes to be produced<br>3. To produce various types of Iron oxide electrodes such as E6020, E6027, E6024, and<br>E6030 by varying the composition of the constituent elements.<br>4. To determine the welded joints performance of the electrodes produced and compare<br>them with the foreign electrodes obtained in the market.<br>5. To carry out the microstructural analysis of the weldments.<br>1.5 Justification<br>In Nigeria, about nine-eight percent of manufacturers in the welding electrode industry<br>have wound up, due to high production cost. The remaining two percent that manage to<br>remain operational sell their coated electrodes at exorbitant prices(Achebo and Dagwa,<br>2009).Consequently there is need for importation of electrodes in to the country to augment<br>for the shortage in the production of electrodes, as a result of this, a large chunk of our foreign<br>exchange is being used in the importation of arc welding electrodes and as such, production of<br>arc welding electrodes locally using mill scales will not only help us in conserving our foreign<br>exchange, but also help us in developing the technology especially as the availability of the<br>24<br>locally produced electrodes has been on the decline in recent years, and in particular the low<br>hydrogen electrode to be produced will be cheaper when compared to the ones obtained in the<br>market.<br>1.6 Research Scope<br>This research work shall focus on the production of arc welding electrodes using mill<br>scales as slag formers. The research will also ensure that the produced electrode are used to<br>weld some specimen and the mechanical properties of the welds from the produced electrode<br>will be compare with that of existing electrodes in the market.
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