Design, construction and performance evaluation of a fixed bed pyrolysis system
Table Of Contents
- DECLARATION ii
CERTIFICATION iii
DEDICATION iv
ACKNOWLEDGEMENT v
ABSTRACT vi
LIST OF FIGURES xi
LIST OF TABLES xiii
LIST OF PLATE xiv
LIST OF APPENDICES xv
NOMENCLATURE xvi
Chapter ONE
INTRODUCTION
- 1.1Background of the Study 1
- 1.2Statement of the Research Problem 2
- 1.3The Present Research 3
- 1.4Aim and Objectives of the Research 3
- 1.5Justification of the Study 3
- 1.6The Scope of the Research 4
Chapter TWO
LITERATURE REVIEW
- 2.1History of Pyrolysis 5
- 2.2Principle of Pyrolysis 5
2.
- 2.1Slow Pyrolysis 7
2.
- 2.2Fast Pyrolysis 8
2.
- 2.3Flash Pyrolysis 9
- 2.3Pyrolysis Reactor 9
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2.
- 3.1Fixed Bed Reactor 10
2.
- 3.2Fluidized Bed Reactor 11
2.3.
- 2.1Bubbling Fluidized Bed Reactor 11
2.3.
- 2.2Circulating Fluidized Bed Reactor 12
2.
- 3.3Ablative Reactor 13
2.
- 3.4Vacuum Pyrolysis Reactor 14
2.
- 3.5Rotating Cone Reactor 15
2.
- 3.6Pyros Reactor 16
2.
- 3.7Auger Reactor 17
2.
- 3.8Plasma Reactor 18
2.
- 3.9Microwave Reactor 19
2.
- 3.10Solar Reactor 20
- 2.4Factors Affecting Pyrolysis of Biomass 21
2.
- 4.1Feedstock Composition 22
2.
- 4.2Feedstock Preparation 23
2.
- 4.3Pyrolysis Temperature Control 24
2.
- 4.4Residence Time 26
2.
- 4.5Moisture Content 26
- 2.5Biomass 27
2.
- 5.1Biomass Conversion Technology 28
2.
- 5.2Feed stock/ material background 29
- 2.6Fourier Transform infra-red (FTIR) 30
- 2.7Gas Chromatography/ Mass Spectroscopy (GC-MS) 30
- 2.8Review of related past works 31
- 2.9Research gap 34
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Chapter THREE
SYSTEM DESIGN AND IMPLEMENTATION
- MATERIALS AND METHODS
- 3.1Materials 35
3.
- 1.1List of Materials 35
- 3.2Methods 36
3.
- 2.1Description of the fixed pyrolysis system 36
3.
- 2.2Design Theory and Equation 37
3.2.2.1Initial design parameters 37
3.2.
- 2.2Stresses in the fixed bed reactor 38
3.2.
- 2.3Reactor Thickness 39
3.2.
- 2.4Insulation 39
3.2.2.4.1Insulation Thickness 39
3.2.
- 2.5Design of the Reactor 42
3.2.
- 2.6Design of the Condenser 45
3.2.
- 2.7Design calculation of the fixed bed pyrolysis system 48
3.
- 2.3Construction of the fixed bed pyrolysis system 51
3.
- 2.4Assembly of the pyrolysis system 53
3.
- 2.5Experimental procedure 55
3.2.
- 5.1Preparation of Feedstock 55
3.2.
- 5.2Operational procedures of the fixed bed pyrolysis system 55
3.
- 2.6Characterization of Palm kernel Shells (PKS) 56
3.2.
- 6.1Proximate analysis of PKS 56
3.2.
- 6.2Ultimate analysis of palm kernel shell 57
3.2.
- 6.3Determination of the calorific value of the palm kernel shell 57
3.
- 2.7Performance evaluation of the fixed bed pyrolysis system 58
3.
- 2.8Effect of pyrolysis parameters 59
3.2.
- 8.1Effect of particle size 59
x
3.2.
- 8.2Effect of temperature 59
3.2.
- 8.3Effect of running time 59
3.
- 2.9Characterization of bio-oil 59
3.2.
- 9.1Ultimate analysis of the bio-oil 60
3.2.
- 9.2Determination of the calorific value of the bio-oil 60
3.2.
- 9.3Fourier Transform infra-red (FTIR) 60
3.2.
- 9.4Gas Chromatography/ Mass Spectroscopy (GC-MS) 60
Chapter FOUR
SYSTEM TESTING AND EVALUATION
- RESULTS AND DISCUSSION
- 4.1Characterization of palm kernel shells (PKS) 62
- 4.2Variation of pyrolysis parameters 63
4.
- 2.1Effect of Particle Size 63
4.
- 2.2Effect of Temperature 65
4.
- 2.3Effect of Running time 67
- 4.3Performance evaluation of the fixed bed pyrolysis system 68
- 4.4Characterization of bio-oil product 69
4.
- 4.1Ultimate analysis of the bio-oil 69
4.
- 4.2FTIR analysis of bio-oil 69
4.
- 4.3GCMS analysis of the Bio-oil 70
- 4.5Cost Estimate 72
Chapter FIVE
SUMMARY, CONCLUSION AND RECOMMENDATIONS
- S AND RECOMMENDATIONS
- 5.1Conclusions 74
- 5.2Recommendations 75
- 5.3Significant Contributions 75
REFRENCES 77
APPENDICES 86
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Thesis Abstract
A fixed bed pyrolysis system has been designed and constructed for obtaining liquid fuel
from palm kernel shell. The major components of the system are fixed bed reactor and
condensate unit. The palm kernel shell in particle form was pyrolized in an externally
heated 90mm diameter and 360mm high fixed bed reactor. The reactor is heated by means
of a rectangular shape manual forge blower with charcoal as the energy source. The
products are char, oil and gas. The parameters varied are feed particle size, reactor bed
temperature and running time. The reactor bed temperature was found to influence the
product yields. The maximum liquid yield was 38.67wt % at 4500C for a feed particle size
of 1.18mm with a running time of 95minutes. The maximum char yield was 70.67wt% at
5500C for a feed particle size of 5mm with a running time of 120minutes. The calorific
value of the palm kernel shells (22.81 MJkg-1) and bio-oil (43.19MJkg-1) were determined.
The reactor efficiency was evaluated at various temperatures. Maximum efficiency of
73.21% indicated that the reactor is efficient enough to produce bio-oil. The bio-oil
products were analysed by Fourier Transform Infra-red Spectroscopy (FTIR) and Gas
Chromatography Mass Spectrometry (GCMS). The FTIR analysis showed that the bio-oil
was dominated by phenol and its derivatives. The phenol, 2-methoxy-phenol and 2, 6-
dimethoxyl phenol that were identified by GCMS analysis are highly suitable for
extraction from bio-oil as value-added chemicals. The highly oxygenated oils need to be
upgraded in order to be used in other applications such as transportation fuels.
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Thesis Overview
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INTRODUCTION<br>1.1 Background of the Study<br>Uninterrupted energy supply is a vital issue for all countries today. Future economic<br>growth crucially depends on the long-term availability of energy from sources that are<br>affordable, accessible, and environmentally friendly. Security, climate change, and public<br>health are closely interrelated with energy (Ramchandra and Boucar, 2011). The standard<br>of living of a given country can be directly related to the per capita energy consumption.<br>The recent world’s energy crisis is due to two reasons: the rapid population growth and the<br>increase in the living standard of societies. The per capita energy consumption is a measure<br>of the per capita income as well as a measure of the prosperity of a nation (Chikaire et al.,<br>2015).<br>Energy supports the provision of basic needs such as cooked food, a comfortable living<br>temperature, lighting, the use of appliances, piped water or sewerage, essential health care<br>(refrigerated vaccines, emergency and intensive care), educational aids, communication<br>(radio, television, electronic mail, the World Wide Web), and transport. Energy also fuels<br>productive activities including agriculture, commerce, manufacturing, industry, and<br>mining. Conversely, lack of access to energy contributes to poverty and deprivation and<br>can contribute to the economic decline. Energy and poverty reduction are not only closely<br>connected with each other, but also with the socioeconomic development, which involves<br>productivity, income growth, education, and health (Nnaji et al., 2010).<br>The high rate of extracting the crude oil from the earth-crust demands for an alternative<br>and dependable source of obtaining energy (Rajput, 2005). This alternative is the energy<br>derived via pyrolysis (a thermal decomposition process that occurs at moderate<br>2<br>temperatures with a high heat transfer rate to the biomass particles and a short hot vapour<br>residence time in the reaction zone) of agricultural and forest residues (generally called<br>biomass). Biomass has been recognized as a major renewable energy source to supplement<br>declining fossil fuel sources of energy. It is the most popular form of renewable energy and<br>currently biofuel production is becoming very much promising. Transformation of energy<br>into useful and sustainable forms that can fulfil and suit the needs and a requirement of<br>human beings in the best possible way is the common concern of the scientists, engineers<br>and technologists. In this contest, bio fuels can be realised through fixed bed pyrolysis<br>system using palm kernel shells as biomass. Fixed bed pyrolysis is more attractive among<br>various thermo-chemical conversion processes because of its simplicity and higher<br>conversion capability of biomass and solid wastes to yield char, liquid and gases (Hossain<br>et al., 2014).<br>1.2 Statement of the Research Problem<br>From the literature reviewed, it is obvious that a lot of research works have been conducted<br>on fixed bed pyrolysis system powered by electric heater. However, it is obvious from the<br>review that fixed bed pyrolysis system powered by electric heater can only be efficiently<br>used where there is steady electricity supply which is the major limitation of this system<br>(especially in Nigeria).<br>The use of stainless steel for the construction of the reactor has a significant effect on the<br>cost of the pyrolysis products. Therefore, there is a need to source for alternative material<br>to minimize the cost at optimum production.<br>3<br>1.3 The Present Research<br>The current work focuses on the design, construction and performance evaluation of a<br>fixed bed pyrolysis system, which will use palm kernel shells to produce bio-fuels. The<br>bio-oil produced can then be used to generate heat and power from small stationary diesel<br>engines, gas turbines and boilers. The agricultural by-products include maize cobs,<br>groundnut shells, palm kernel shells, rice and millet husks, millet stalks, sorghum stalks,<br>sugar cane bagasse, maize stalks and cotton stalks among others. However, this research<br>will focus on palm kernel shells because of its availability.<br>1.4 Aim and Objectives of the Research<br>The aim of this research is to design and construct an externally heated fixed bed pyrolysis<br>system for the production of alternative liquid oil from palm kernel shells.<br>Therefore, the specific objectives of this research are to:<br>i. design a fixed bed pyrolysis system.<br>ii. construct the fixed bed pyrolysis system.<br>iii. evaluate the performance of the fixed bed pyrolysis system to determine its<br>effectiveness in bio-oil production.<br>iv. characterise the bio-oil produced from the fixed bed pyrolysis system using<br>FTIR and GCMS analyses.<br>1.5 Justification of the Study<br>Nigeria is blessed with abundant renewable energy resources such as hydroelectric, solar,<br>wind, tidal, and biomass, there is a need to harness these resources and chart a new energy<br>future for Nigeria. To enhance the developmental trend in the country, there is every need<br>to support the existing unreliable energy sector with a sustainable source of power supply<br>through pyrolysis of biomass.<br>4<br>There are several benefits of introducing electricity to rural communities. While obvious<br>reasons include social gains like lightening, cooking and water pumping, electricity will<br>help to stem the flow of rural-urban migration which is a common problem in many<br>developing countries like Nigeria. Introduction of electricity also helps to provide<br>productive employment in rural areas thereby creating a positive impact on economic as<br>well as social growth. Fixed bed pyrolysis when combined with a boiler can provide<br>efficient and affordable source of energy thereby boosting rural education and<br>development, since it uses agricultural waste as a fuel source. Bio-oil generated can either<br>be used for electricity production in a gas turbine or generate steam in a boiler.<br>1.6 The Scope of the Research<br>The scope of this research is:<br>i. Design, construction and performance evaluation of a fixed bed pyrolysis<br>system, which will use palm kernel shells as feed materials to produce biofuels.<br>ii. The emphasis of the study is on the production of a liquid fuel from 1.5kg per<br>sample of palm kernel shells using fixed bed pyrolysis system. The char<br>product will be also quantified.<br>5
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