Quality characteristics of underground water resources in nkanu east and nkanu west local government areas of enugu state, nigeria | Blazingprojects Postgraduate Thesis
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Quality characteristics of underground water resources in nkanu east and nkanu west local government areas of enugu state, nigeria

 

Table Of Contents


  • Title Page ————————————————————————- i Approval Page ——————————————————————- ii Certification ———————————————————————- iii Dedication ———————————————————————— iv Acknowledgement ————————————————————– v Abstract ————————————————————————— vi Table of Contents ————————————————————- vii List of Tables ——————————————————————– xi List of Figures ——————————————————————- xii

Chapter ONE

INTRODUCTION

  • 1.0Introduction—————————————————————— 1
  • 1.1Underground water quality ———————————————– 1
  • 1.2Background of Study —————————————————— 2
  • 1.3Scope of Study————————————————————– 3
  • 1.4Objective of Study ——————————————————— 4

Chapter TWO

LITERATURE REVIEW

  • 2.0Literature Review———————————————————– 5
  • 2.1Water ————————————————————————- 5 2.
  • 1.1Properties of water ——————————————————- 5 2.
  • 1.2Uses of Water ———————————————————— 6
  • 2.2Types of water resources————————————————– 7 2.
  • 2.1Underground water —————————————————— 7 2.
  • 2.2Surface water ————————————————————- 8 2.
  • 2.3Water in the atmosphere ———————————————— 12 viii
  • 2.3Pollution ——————————————————————— 12 2.
  • 3.1Water pollution ———————————————————– 13 2.3.
  • 1.1Organic pollutants —————————————————– 13 2.3.
  • 1.2Inorganic pollutants ————————————————— 15 2.3.
  • 1.3Sediments pollutants ————————————————- 16 2.3.
  • 1.4Radioactive materials ———————————————— 16 2.3.
  • 1.5Thermal pollutants —————————————————- 17 2.
  • 3.2Underground water pollution/pollutant —————————– 17 2.3.
  • 2.1Point-source pollution ———————————————— 19 2.3.
  • 2.2Non-point source pollution —————————————— 19 2.3.
  • 2.3Chemical pollution —————————————————- 21 2.3.
  • 2.4Biological pollution ————————————————— 22 2.3.
  • 2.5Physical/Natural pollution ——————————————- 24
  • 2.4Water Analysis ————————————————————- 25 2.
  • 4.1Physical examination —————————————————- 25 2.4.
  • 1.1Temperature ———————————————————— 25 2.4.
  • 1.2Turbidity —————————————————————- 25 2.4.
  • 1.3pH————————————————————————- 27 2.4.
  • 1.4Total dissolved solids ———————————————— 27 2.4.
  • 1.5Conductivity ———————————————————— 28 2.4.
  • 1.6Colour——————————————————————– 28 2.
  • 4.2Chemical examination ————————————————– 28 2.4.
  • 2.1Hardness —————————————————————- 28 2.4.
  • 2.2Alkalinity—————————————————————- 30 2.4.
  • 2.3Calcium—————————————————————— 30 2.4.
  • 2.4Magnesium————————————————————– 31 2.4.
  • 2.5Chloride —————————————————————– 31 2.4.
  • 2.6Nitrate——————————————————————– 31 ix 2.4.
  • 2.7Phosphate ————————————————————— 32 2.4.
  • 2.8Potassium ————————————————————— 32 2.4.
  • 2.9Sulphate —————————————————————– 33 2.4.
  • 2.10Sodium—————————————————————– 33 2.4.
  • 2.11Cadmium ————————————————————– 34 2.4.
  • 2.12Chromium ————————————————————- 35 2.4.
  • 2.13Copper—————————————————————— 36 2.4.
  • 2.14Iron———————————————————————- 37 2.4.
  • 2.15Lead——————————————————————— 38 2.4.
  • 2.16Nickel —————————————————————— 38 2.4.
  • 2.17Zinc ——————————————————————— 39 2.
  • 4.3Microbiological examination —————————————– ` 39

Chapter THREE

RESEARCH METHODOLOGY

  • 3.0Materials and Methods —————————————————- 41
  • 3.1Sample collection———————————————————– 41
  • 3.2Method of analysis ——————————————————– 43 3.
  • 2.1Turbidity —————————————————————— 43 3.
  • 2.2Temperature ————————————————————– 43 3.
  • 2.3Colour ———————————————————————- 43 3.
  • 2.4Total dissolved solid —————————————————- 43 3.
  • 2.5pH ————————————————————————— 44 3.
  • 2.6Conductivity ————————————————————– 44 3.
  • 2.7Total alkalinity ———————————————————– 44 3.
  • 2.8Total hardness ———————————————————— 45 3.
  • 2.9Calcium——————————————————————– 46 3.
  • 2.10Magnesium ————————————————————– 47 3.
  • 2.11Chloride —————————————————————— 47 x 3.
  • 2.12Nitrate ——————————————————————– 48 3.
  • 2.13Sulphate —————————————————————— 49 3.
  • 2.14Phosphate —————————————————————- 49 3.
  • 2.15Sodium ——————————————————————- 50 3.
  • 2.16Potassium —————————————————————- 50 3.
  • 2.17Heavy metals determination —————————————– 51 3.
  • 2.18Bacteriological examination—————————————— 52

Chapter FOUR

DATA PRESENTATION AND ANALYSIS

  • 4.0Results and Discussions————————————————— 53
  • 4.1Turbidity ——————————————————————— 55
  • 4.2Colour ———————————————————————— 55
  • 4.3Conductivity—————————————————————– 57
  • 4.4Total dissolved solid ——————————————————- 57
  • 4.5pH —————————————————————————– 58
  • 4.6Total hardness, calcium hardness and magnesium hardness ——- 59
  • 4.7Total alkalinity————————————————————– 61
  • 4.8Nitrate ———————————————————————— 62
  • 4.9Phosphate ——————————————————————– 62
  • 4.10Sulphate——————————————————————— 63
  • 4.11Chloride——————————————————————— 63
  • 4.12Sodium and potassium————————————————— 64
  • 4.13Heavy metals ————————————————————– 67
  • 4.14Total coliform ————————————————————- 69 Conclusion and Recommendation ——————————————- 69 References ———————————————————————– 71 xi

Thesis Abstract

Physicochemical and bacteriological analyses of underground water resources
in Nkanu East and Nkanu West Local Government Areas of Enugu state,
Nigeria were carried out to evaluate the potability and quality of the rural water
supplies and to provide baseline data for future quality assessment.
Underground water samples were collected from ten different boreholes in
Nkanu East and Nkanu West LGAs. The parameters measured include
temperature, colour, pH, electrical conductivity, turbidity, total dissolved
solids, total hardness, calcium hardness, magnesium hardness, total alkalinity,
chloride, sulphate, phosphate, nitrate, sodium, potassium, lead, chromium,
copper, cadmium, nickel, iron, zinc and total coliform. The water showed near
neutral pH (6.4- 8.2) favourably comparable to the WHO recommended range
of 6.5-8.5, with moderate permanent hardness of 2.5-289 mg/L. Conductivity
and total dissolved solids values for Amechi Idodo (4360 μs/cm, 2650 mg/L)
and Mbulu Owo (4880 μs/cm, 2930 mg/L) were higher than the WHO
guideline values of 1660 μs/cm and 1000 mg/L, respectively. Concentrations of
most trace metals and all anions were below the WHO guideline values.
However, iron,cadmium and chromium occurred at levels slightly above the
WHO permissible limit. Total coliform count in Amechi Idodo and Mbulu Owo
exceeded the WHO guideline value of zero. The underground waters studied
are good for drinking provided they are boiled to remove microbial
contamination.

 


Thesis Overview

<p> 1.0 Introduction<br>1.1 Underground water quality<br>Water is the matrix of life and forms the bulk of the weight of the living<br>cells. The resources of usable water have been diminishing and are unable to<br>meet the variety of needs of modern civilization. Water as the carrier of<br>pathogenic microorganisms, can cause immense harm to public health.<br>Waterborne diseases include typhoid and paratyphoid fever, dysentery and<br>cholera, polio and infectious hepatitis [1].<br>Many developing countries are witnessing a stage of development<br>where water from shallow wells and boreholes are gradually supplementing the<br>original sources of drinking water (surface water). The preference for<br>underground water to surface water is borne out of the belief that before<br>underground water can be distributed as tap water it must always be subjected<br>to some purification, while in practice, underground waters are filtered by<br>natural processes as they pass through columns of soils, sands, strata, or<br>sedimentary layers of rocks and are usually clear of solid materials as they<br>come from the aquifer, particularly if they are deep seated ones. The intricate<br>pore spaces or water passage ways of the aquifer materials act as a fine filter<br>and remove small particles of clay or any other fines [2]. Organic materials<br>decay or are destroyed in transit. Thus, the dirtiest and most polluted sewage<br>2<br>water may become clear of suspended/particulate solid materials once it has<br>gone through a thick bed of sand or geologic and pedologic units. As a result of<br>this natural self-cleansing of polluted water by deep-seated aquifers, physical<br>and biological aspects of pollution may not pose serious problems in<br>underground waters [2].<br>Thus, underground water may not be treated before use and is believed<br>to be free from pollution. In spite of all this, underground waters may have<br>pollutants that not only depend on the geology, pedology, and mineralogy of<br>the formations it flows through but also on the constituent<br>pollutants/contaminants in the water that recharges the underground water.<br>Unsatisfactory colour and taste are easily detected and are good indicators for<br>underground waters of poor quality. Some underground waters taste of iron,<br>others may have a disagreeable odor. Borehole waters must, as a rule, be<br>analyzed for chemical contaminants before the water is distributed and supplied<br>to households [2].<br>1.2 Background of Study<br>The area of study is Nkanu East and Nkanu West. A Local Government<br>Area in Enugu State, Nigeria, Nkanu East borders Ebonyi State to the east. Its<br>Headquarters is Amagunze. It is a rural area with a population of about 148,<br>774 and land mass of approximately 795 km2.. Nkanu West has its<br>Headquarters at Agbani. It has an area of 225 km2 and a population of 146,695.<br>3<br>The major occupation in these areas is farming. The various communities<br>making up the two local government areas live in small villages, which still<br>have considerable natural surroundings. Although there are springs and<br>streams, most of the communities rely on boreholes for their water supply due<br>to proximity and modernity [3].<br>Due to increased use of fertilizers and pesticides in this areas part of<br>which is leached into the underground water through the soil, there is increased<br>risk of pollution of these boreholes. Enugu, the state of study was previously<br>mined for coal and underground water pollution is an ever present risk in areas<br>of mining. Also most of the people use pit toilets which are sources of<br>underground water pollution [2].<br>1.3 Scope of Study<br>Samples of water from ten boreholes in the two LGAs specifically in<br>Amechi Idodo, Mbulu Owo, Umueze, Agbani, Ugbawka, Isiogbo Nara,<br>Akpugo, Amurri, Nara Unateze and Amodu Awkunanaw are to be collected.<br>Physicochemical, bacteriological and trace metal analysis comprising of<br>temperature, colour, pH, electrical conductivity, turbidity, total dissolved<br>solids, total alkalinity, total hardness, calcium, magnesium, chloride, nitrate,<br>phosphate, sulphate, sodium, potassium, total coliform, lead, copper, zinc,<br>chromium, cadmium, and nickel are to be undertaken and values obtained are<br>to be compared with World Health Organization (WHO) guideline values.<br>4<br>1.4 Objective of Study<br>There are yet no reported physicochemical or bacteriological studies of<br>underground water resources in Nkanu East and Nkanu West Local government<br>Areas. Therefore we set out to analyze borehole water samples from these areas<br>in order to ascertain the potability and safety of the water by comparing the<br>concentration levels with set standards and to procure the present quality status<br>as baseline data for future periodic monitoring of the underground water quality<br>in this area.<br>5 <br></p>

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