Quality assessment of borehole waters in enugu urban
Table Of Contents
- Title – – – – – – – – – – i
Abstract – – – – – – – – – ii
Acknowledgement – – – – – – – iii
Certification – – – – – – – – iv
Dedication – – – – – – – – v
Table of contents – – – – – – – vi
List of figures – – – – – – – – ix
List of tables – – – – – – – – x
Chapter ONE
INTRODUCTION
- 1.0Introduction – – – – – – – 1
- 1.1Background Of The Study – – – – – 4
- 1.2Scope Of Study – – – – – – – 8
- 1.3Aims – – – – – – – – – 8
- 1.4Objectives Of Study – – – – – – 8
Chapter TWO
LITERATURE REVIEW
- 2.0Literature Review – – – – – – 9
- 2.1Pollution – – – – – – – – 9
- 2.2Pollutants – – – – – – – – 10
- 2.3Water – – – – – – – – 13
2.
- 3.1Properties Of Water – – – – – – 14
2.
- 3.2Uses Of Water – – – – – – – 17
2.
- 4.Types Of Water Resources And The Environment 20
2.
- 4.1Atmospheric Water Resource Systems – – 20
2.
- 4.2Surface Water Resources and the Environment 22
2.
- 4.3Ground Water – – – – – – – 27
vii
- 2.5Contaminants/Pollutants Affecting Groundwater
Quality – – – – – – – – 29
2.
- 5.1Agricultural Contamination – – – – 30
2.
- 5.2Sanitary Landfills And Garbage Dumps – – 31
2.
- 5.3Biological Pollutant/Contaminants in
Ground Water – – – – – – – 33
2.
- 5.4Heavy Metal Contamination – – – – 38
- 2.6Contaminant Transport – – – – – 41
- 2.7Water Analysis – – – – – – – 47
2.
- 7.1Physical Examination – – – – – 47
2.
- 7.2Chemical Examination – – – – – 50
2.
- 7.3Microbial Examination – – – – – 55
Chapter THREE
RESEARCH METHODOLOGY
- 3.0Materials and Methods – – – – – 56
- 3.1Sample Collection – – – – – – 56
- 3.2Method of Analysis – – – – – – 57
3.
- 2.1Determination of Color – – – – – 57
3.
- 2.2pH Determination – – – – – – 58
3.
- 2.3Electrical Conductivity Determination – – 59
3.
- 2.4Determination of Total Hardness – – – 60
3.
- 2.5Determination of Calcium Hardness – – – 63
3.
- 2.6Determination of Magnesium Hardness – – 65
3.
- 2.7Determination of Alkalinity – – – – 65
3.
- 2.8Determination of Total Solids (TS) – – – 68
3.
- 2.9Determination of Total Dissolved Solids (TDS) – 69
3.2.10Determination of Total Suspended Solids (TSS) 70
viii
3.2.11Determination of Chloride Content – – – 70
3.
- 2.12Sulphate Determination – – – – – 73
3.
- 2.13Phosphate Determination – – – – 74
3.
- 2.14Nitrate Determination – – – – – 75
3.
- 2.15Heavy Metals Determination – – – – 75
3.
- 2.16Microbial Examination – – – – – 76
Chapter FOUR
DATA PRESENTATION AND ANALYSIS
- Results and Discussions- – – – – – – 79
Conclusion – – – – – – – – 99
References – – – – – – – – 101
Thesis Abstract
The quality assessment of borehole and well waters from ten
locations in Enugu urban area were studied and compared
with World Health Organisation standards. The parameters
measured include temperature, color, pH, electrical
conductivity, total hardness, calcium hardness, magnesium
hardness, total solids, total dissolved solids, total suspended
solids, alkalinity, chloride, sulphate, phosphate, nitrate,
copper, cadmium, zinc, lead, iron, and total coliform. Langelier
Saturation and Ryznar Stability Indices were also calculated
for some of these parameters. The results obtained at daily
intervals were plotted and they showed pollution of seven of
the boreholes. Concentrations of Cadmium were high above
the limit in six of the boreholes while concentrations of lead
and phosphates were high in only two of the boreholes, with
respect to the WHO permissible limits for potable water. All
the waters show presence of coliform and corrosion potentials.
Consequently, these ground waters in this study require
treatment before they will be good for human consumption.
Thesis Overview
<p>
</p><p>INTRODUCTION<br>The use of water by man is as old as the existence<br>of human beings since water, which is a natural<br>resource, is indispensable to life.<br>Water is a common chemical substance that is<br>essential for the survival of all known forms of life. It is<br>used in vast quantities for drinking purposes, and even<br>in greater quantities for washing, bleaching, dyeing,<br>cooling, raising steam to drive engines or turbines to<br>generate electricity and in other industrial processes far<br>too numerous to mention [1,2].<br>As a result of industrialisation and urbanisation,<br>people migrate to townships and the population in these<br>cities become too high; so is the need for water. Although<br>surface water such as lakes, rivers, streams and springs<br>are easily accessible, there is a great quest for people to<br>drill borehole ground waters which are thought to be of<br>better quality[3]. It is pertinent to observe that there are<br>2<br>several human activities, which have indirect and<br>devastating effects on ground water quality. Such<br>activities include accidental or unauthorized release of<br>chemical substances, discharge of untreated effluents,<br>leaching of noxious liquids from solid waste deposits,<br>surface runoff, untreated sewage, from population<br>around the area [4,5]. This is because these pollutants or<br>contaminants are carried by water and water moves<br>easily through the soil and underlying rocks. This occurs<br>particularly where the soil is sandy, gravelley or shallow<br>or over porous limestone bedrock [6].<br>It is therefore the concern of scientists to ensure<br>that the supply of water is maintained at sufficient purity<br>for the masses to use. All the water from the borehole to<br>the consumption level ought to meet the standards laid<br>down by World Health Organization for drinking water to<br>make the water potable. Substandard water samples can<br>lead to diseases such as typhoid fever, dysentery, cholera<br>and other types of gastrointestinal disturbances[7].For<br>3<br>drinking water to be safe, the concentration of<br>undesirable substances should not exceed the levels<br>established by World Health Organization[8] as shown in<br>Table 1below<br>Table 1: WHO Permissible Values<br>Parameters WHO LIMIT Color 5 – 25 units Taste and odor Unobjectionable Turbidity 5 units pH 6.0 – 8.5 Electrical conductivity (µmhoscm–1) 50 Alkalinity (mg–1) CaCO3 100 Total solids (mg-1) 1000 Total dissolved solids (mgl–1) 1000 Total suspended solid (mgl–1) 500 Total hardness (mgl–1) CaCO3 500 Calcium hardness (mg-1) CaCO3 500 Magnesium (mg-1) CaCO3 500 Sulphate (mgl–1) 400 Nitrate (mgl–1) 50 Phosphate (mgl–1) 1.0 Chloride (mg-1) 250 Iron (mgl–1) 0.3 Manganese (mgl–1) 0.05 Lead (mgl–1) 0.05 Copper (mgl–1) 1.0 Zinc (mgl–1) 5.0 Cadmium (mgl–1) 0.05 Fecal coliform count/100ml 0 Total coliform count/100ml 0<br>4<br>This was focused on the quality of borehole waters in<br>Enugu urban in relation to World Health Organization<br>standards, to ascertain their potability.<br>1.1. BACKGROUND OF THE STUDY<br>Nigeria is located in West Africa and has variable<br>terrain. The climate ranges from equatorial in the south<br>to tropical in the centre and arid in the north. Climatic<br>variations influence the vegetations, ranging from<br>mangrove swamps in the south, tropical rainforest in the<br>centre, Savannah in the north and Sahel Savannah in<br>the north-east. The annual rainfall varies from 4000mm<br>in the south and 250mm in the north, with a national<br>average of 1180mm [9]. Geological reports gave rock<br>types as Precambrian basement in the southwest, south<br>east and north-central. The rocks include gneisses,<br>schists, migmatites, pegmatite, charnockitic and quartz<br>schist [10]. The study area Enugu urban is found in<br>Enugu State, southeast Nigeria, situated on longitude<br>5<br>70301 0E and latitude 60301 0N and has tropical<br>vegetation. The major climatic seasons are wet or rainy<br>season, which begins in March or April, and ends in<br>October and the dry season, which begins in November<br>and ends in March or April.<br>Groundwater is an important water resource in both<br>the urban and rural areas of Nigeria. Enugu which was<br>previously mined for coal produced acid wastes that were<br>rich in metal elements like Pb, Cu, Zn, As, Mn and Fe.<br>Most of these are toxic at fairly low concentrations. The<br>coal mining at Enugu especially, has the potential of<br>posing an acid mine drainage[11]. Though groundwater is<br>considered to be aesthetically acceptable for domestic<br>use, presence of poorly designed pit latrines, poor solid<br>waste management as well as poor and inadequate water<br>protection, may lead to contamination of groundwater<br>with pathogenic bacteria.<br>6<br>Also there is a growing fear of environmental<br>pollution by Lead (Pb) in the state generally due to the<br>littering of the streets with storage batteries and to a<br>lesser degree from gasoline burning engines and smokes<br>from other fuels.</p><p>Fig 1: Map of Nigeria<br>7</p><p>Fig. 1: Map of Nigeria<br>Fig. 2: Map of Enugu showing study Area</p><p>Population</p><p>Industries</p><p>Borehole</p><p>Main road</p><p>Market</p><p>Airport<br>KEY<br>8<br>1.2. SCOPE OF STUDY<br>Analysis of samples of borehole waters hand dug-wells<br>and control (distilled) water to find temperature, color,<br>pH electrical conductivity, total solids (TS), total dissolved<br>solids (TDS), total suspended solids (TSS), total hardness,<br>calcium hardness, magnesium hardness, alkalinity,<br>chloride, SO4 , NO3 , PO4 , Pb, Cu, Zn, Cd, Fe<br>contents, total coliform (TC) counts and Langelier<br>Satuation Index (LSI) using some of the parameters in<br>accordance to the standard method.</p><p>1.3. AIMS<br>– To improve man’s health, through the taking of potable<br>water<br>– To determine the extent of contamination of the waters<br>1.4 OBJECTIVES OF STUDY<br>The objectives of the study were to examine the<br>physico-chemical and bacteriological quality of water<br>from ten boreholes in Enugu urban, and to determine the<br>corrosion potential of the water.</p>
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