Heavy metal distribution in sediment of akpabuyo stream, cross river basin southeastern nigeria.. | Blazingprojects Postgraduate Thesis
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Heavy metal distribution in sediment of akpabuyo stream, cross river basin southeastern nigeria..

 

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Thesis Abstract

Heavy metal pollution in aquatic environments is a significant environmental concern due to its potential adverse effects on ecosystems and human health. This study focused on assessing the distribution of heavy metals in the sediment of Akpabuyo Stream in the Cross River Basin, Southeastern Nigeria. The concentrations of six heavy metals (lead, cadmium, copper, zinc, nickel, and chromium) were analyzed in sediment samples collected from different locations along the stream. The results of the study revealed varying levels of heavy metal contamination in the sediment of Akpabuyo Stream. Lead concentrations ranged from 2.14 mg/kg to 7.89 mg/kg, with the highest levels observed at the downstream sites. Cadmium concentrations ranged from 0.11 mg/kg to 0.45 mg/kg, also showing higher levels at the downstream locations. Copper concentrations varied from 10.25 mg/kg to 35.67 mg/kg, with the highest values recorded at the midstream sites. Zinc concentrations ranged from 15.89 mg/kg to 58.32 mg/kg, with the highest levels found at the upstream sampling points. Nickel concentrations varied from 8.76 mg/kg to 30.41 mg/kg, showing an increasing trend from upstream to downstream locations. Chromium concentrations ranged from 2.34 mg/kg to 9.78 mg/kg, with the highest levels observed at the midstream sites. Overall, the results indicate that the sediment of Akpabuyo Stream is contaminated with varying levels of heavy metals, with higher concentrations generally observed at the downstream locations. The findings of this study highlight the potential environmental risks associated with heavy metal pollution in the stream and emphasize the importance of regular monitoring and management of water bodies in the Cross River Basin. Understanding the distribution of heavy metals in sediment is crucial for assessing the potential risks to aquatic ecosystems and human health. The findings of this study provide valuable information for environmental managers and policymakers to develop strategies for mitigating heavy metal pollution in the Akpabuyo Stream and other water bodies in the Cross River Basin. Further research is needed to investigate the sources of heavy metal contamination in the stream and to assess the long-term impacts of this pollution on the environment and public health.

Thesis Overview

<p> </p><div><p><strong>1.1 INTRODUCTION</strong></p><p>Heavy metals pollution of aquatic ecosystem is becoming a potential global problem, pollution typically refers to chemicals or other substance in concentration greater than it would occur under natural conditions. Water pollution is the introduction by man of substances into the aquatic environment resulting from deleterious effect as harm to human health (FAO 1990).The presence of increased level of heavy metals in the aquatic environment has been of much concern for the past decades due to adverse effect of some metals on living organisms in food chains leading to man. Pollutants are the cause of major water quality degradation around the world. Several toxic metals which are important to the environment and human health have been detected in aquatic media. These toxic metals include the non-essential meals and are no importance to humans (Borgman and Norwood 2002).</p><p>Trace amount of heavy metals are always present in fresh water from terrigenous sources such as weathering of rocks resulting into geo-chemical recycling of heavy metal elements in these ecosystem. Trace elements may be immobilised within the stream sediments and could be involved in absorption, co-precipitation and complex formation. Sometimes they are co-adsorbed with other elements as oxides, hydroxides of Fe, Mn, or may occur in particulate form.</p><p>Heavy metal may enter into aquatic ecosystem from anthropogenic sources, such as industrial wastewater discharge, sewage wastewater, fossil fuel combustion, and atmospheric deposition. Trace element in stream sediment compartment can be used to reveal the history and intensity of local and regional pollution. In this work, the of stream sediment contamination was assess using geo-accumulation index.</p><p><strong>1.2 AIMS AND OBJECTIVES</strong></p><p>The main objectives of the current study area are:</p><p>To assess the extent and degree of metals, and the origin of these metals, using the geo-accumulation index of the metals.</p><p>To determine the total content of heavy metals in surface sediments of Akpabuyo.</p><p>To estimate the anthropogenic input and to assess the pollution status on the area.</p><p><strong>1.3 STUDY AREA</strong></p><p>The study area which is located in Akpabuyo, Cross River State lies between longitudes 80 22I 30II E – 80 30I 0II E and latitude 40 52I 30II N – 40 57I 30II N (fig 2). With an area of 126,4032 Square Km. Although many stream samples where collected but few was selscted for the heavy metal analysis. The various Locations in Akpabuyo which sediment samples were collected and used to carry out the analysis are Esuk Mbat stream(L1), Esuk Ekpo Eyo Stream(L2), Ikot Akwa Stream(L3), Dan Archibong Stream(L4), Itu Stream(L5), Ikot Ndarake Stream(L6), Asioha Stream(L7), Ikot Ekpo Ene Stream(L8), Ekpene Ikot Imo Stream(L9), Ikot Nakanda(L10), and their following coordinate shown respectively (table 1.3) . It originate from a hilly region and flows through several villages and farmland.</p><p></p></div><h3></h3><br> <br><p></p>

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