Levels of polycyclic aromatic hydrocarbon in fresh water fish dried under different drying regimes | Blazingprojects Postgraduate Thesis
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Levels of polycyclic aromatic hydrocarbon in fresh water fish dried under different drying regimes

 

Table Of Contents


Chapter ONE

INTRODUCTION

  • 1.1Introduction
  • 1.2Background of Study
  • 1.3Problem Statement
  • 1.4Objective of Study
  • 1.5Limitation of Study
  • 1.6Scope of Study
  • 1.7Significance of Study
  • 1.8Structure of the Research
  • 1.9Definition of Terms

Chapter TWO

LITERATURE REVIEW

  • 2.1Overview of Polycyclic Aromatic Hydrocarbons (PAHs)
  • 2.2Sources of PAHs in the Environment
  • 2.3Health and Environmental Impacts of PAHs
  • 2.4Analytical Methods for PAH Detection
  • 2.5Bioaccumulation of PAHs in Aquatic Organisms
  • 2.6Regulations and Guidelines for PAH Levels
  • 2.7Studies on PAHs in Freshwater Fish
  • 2.8Effects of Drying on PAH Levels
  • 2.9Factors Affecting PAH Concentrations
  • 2.10Summary of Literature Review

Chapter THREE

RESEARCH METHODOLOGY

  • 3.1Research Design and Methodology
  • 3.2Sampling Techniques and Sample Size
  • 3.3Data Collection Methods
  • 3.4Laboratory Analysis of PAHs
  • 3.5Statistical Analysis
  • 3.6Ethical Considerations
  • 3.7Research Limitations
  • 3.8Data Interpretation Techniques

Chapter FOUR

DATA PRESENTATION AND ANALYSIS

  • 4.1Overview of Research Findings
  • 4.2PAH Levels in Freshwater Fish Samples
  • 4.3Comparison of PAH Levels in Different Drying Regimes
  • 4.4Factors Influencing PAH Concentrations
  • 4.5Discussion on Bioaccumulation Patterns
  • 4.6Implications for Human Health
  • 4.7Comparison with Regulatory Standards
  • 4.8Recommendations for Future Research

Chapter FIVE

SUMMARY, CONCLUSION AND RECOMMENDATIONS

  • 5.1Summary of Findings
  • 5.2Conclusions
  • 5.3Contributions to the Field
  • 5.4Practical Implications
  • 5.5Recommendations for Stakeholders
  • 5.6Suggestions for Further Studies

Thesis Abstract

Preservation of fish by drying over different types of heat regimes have been known. However, there has not been a comprehensive comparison in terms of the possible contamination associated with these drying regimes. This work was set to evaluate the levels of PAHs that are likely to accumulate in the bodies of fresh water fishes dried under heat from charcoal, sun (sun drying), electric oven and polythene augmented drying regimes (burning of used cellophone materials). The levels of sixteen PAHs were determined in fish samples harvested from Otuocha River in Anambra State, Nigeria. The fish samples were dried, pulverized and subjected to soxhlet extraction using n-hexane at 600c for 8hrs. The water content of the eluants were further removed with florisil clean-up before Gas chromatographic – mass spectrometric analysis. Results obtained showed that sun-dried fish had PAHs concentration to be 35.7+ 0.2µg/g; oven dried gave 47.7+ 0.2µg/g and charcoal dried 79.53+ 0.2µg/g, while drying with firewood resulted in 188.1+ 0.2µg/g. Charcoal drying augmented with polythene resulted into PAHs level of 166.2+ 0.1µg/g while fish dried under heat generated from burning firewood and polythene material resulted into PAHs concentration of 696.3+0.2µg/g. Preliminary analysis of the fresh water samples and the undried fish samples (control) revealed that the fresh water contained total PAHs level of 2.86+ 0.1µg/ml, while the fresh fish 4.97+ 0.2µg/g. The concentration of PAHs in all the dried fish under different drying agents were significantly higher than the control.

Thesis Overview

<p> </p><p><strong>1.1 INTRODUCTION</strong></p><p>Polycyclic aromatic hydrocarbons (PAHs) are a group of organic compounds consisting of two or more fused benzene rings (linear, cluster or angular arrangement), or compounds made up of carbon and hydrogen atoms grouped into rings containing five or six carbon atoms. They are called “PAH derivatives” when an alkyl or other radical is introduced to the ring, and heterocyclic aromatic compounds (HACs) when one carbon atom in a ring is replaced by a nitrogen, oxygen or sulphur atoms. PAHs originate mainly from anthropogenic processes particularly from incomplete combustion of organic fuels. PAHs are distributed widely in the atmosphere. Natural processes, such as volcanic eruptions and forest fires, also contribute to an ambient existence of PAHs (Suchanova <em>et al</em>., 2008). PAHs can be present in both particulate and gaseous phases, depending on their volatility. Low molecular weight PAHs (LMW PAHs) that have two or three aromatic rings (molecular weight from 152 to 178g/mol) are emitted in the gaseous phase, while high molecular weight PAHs (HMW PAHs), molecular weight ranging from 228 to 278g/mol, with five or more rings, are emitted in the particulate phase, (ATSDR, 1995) . In the atmosphere, PAHs can undergo photo-degradation and react with other pollutants, such as sulfur dioxide, nitrogen oxides, and ozone. Due to widespread sources and persistent characteristics, PAHs disperse through atmospheric transport and exist almost everywhere. There are hundreds of PAH compounds in the environment but in practice PAH analysis is restricted to the determination of six (6) to sixteen (16) compounds. Human beings are exposed to PAH mixtures in gaseous or particulate phases in ambient air.</p> <br><p></p>

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