Thesis Abstract

Abstract
Metal-organic frameworks (MOFs) have emerged as promising materials for various applications due to their tunable properties and high surface areas. This thesis focuses on the synthesis and characterization of novel MOFs for gas storage applications, with a specific emphasis on enhancing gas storage capacities for practical use. The research methodology involved the design and synthesis of MOFs using different metal ions and organic linkers, followed by detailed characterization using various analytical techniques. Gas adsorption studies were conducted to evaluate the gas storage capacities of the synthesized MOFs, with a focus on hydrogen and methane storage. Chapter One provides an introduction to the research topic, outlining the background of the study, problem statement, objectives, limitations, scope, significance, structure of the thesis, and definition of key terms. Chapter Two presents a comprehensive literature review covering the theoretical foundations of MOFs, gas storage principles, previous studies on MOF synthesis, characterization techniques, and gas adsorption properties of MOFs. Chapter Three details the research methodology, including the synthesis procedures for the novel MOFs, characterization techniques such as X-ray diffraction, scanning electron microscopy, and gas adsorption studies. The chapter also discusses the optimization of synthesis conditions to enhance the gas storage capacities of the MOFs. In Chapter Four, the findings of the study are elaborated, presenting the characterization results of the synthesized MOFs and their gas adsorption properties. The discussion focuses on the relationship between the structural properties of MOFs and their gas storage performances, highlighting the key factors influencing gas adsorption capacities. Lastly, Chapter Five provides a comprehensive conclusion and summary of the thesis, summarizing the key findings and contributions of the study. The implications of the research findings for gas storage applications are discussed, along with recommendations for future research directions in the field of MOFs for gas storage. Overall, this thesis contributes to the advancement of MOF research by synthesizing and characterizing novel MOFs with enhanced gas storage capacities. The findings of this study have the potential to impact the development of efficient gas storage materials for various industrial applications, particularly in the fields of hydrogen and methane storage.

Thesis Overview

The research project titled "Synthesis and Characterization of Novel Metal-Organic Frameworks for Gas Storage Applications" aims to investigate and develop innovative metal-organic frameworks (MOFs) for potential applications in gas storage. MOFs are a class of crystalline materials composed of metal ions or clusters linked by organic ligands, known for their high porosity and tunable properties. Gas storage is a critical area of research due to the increasing demand for efficient and sustainable energy storage solutions. The primary objective of this research is to synthesize novel MOFs with enhanced gas storage capabilities through a systematic approach that involves the design, synthesis, characterization, and evaluation of these materials. By exploring different metal ions, organic ligands, and synthesis methods, the study aims to tailor the properties of MOFs to optimize gas storage performance, such as high gas adsorption capacity, selectivity, and stability. The project will begin with a comprehensive literature review to establish the current state-of-the-art in MOF synthesis, gas storage applications, and related research. This review will provide a foundation for the research methodology, which will encompass the synthesis of MOFs using various techniques such as solvothermal, microwave-assisted, and mechanochemical methods. The synthesized MOFs will then be characterized using a range of analytical techniques including X-ray diffraction, scanning electron microscopy, thermal analysis, and gas adsorption measurements. The research will focus on elucidating the structure-property relationships of the synthesized MOFs to understand how different parameters influence their gas storage performance. This will involve investigating factors such as pore size, surface area, functional groups, and metal-ligand interactions on the gas adsorption behavior of the materials. The results obtained from these characterization studies will be used to optimize the synthesis parameters and design new MOFs with improved gas storage properties. The discussion of findings will involve a detailed analysis of the experimental results, highlighting the key observations, trends, and implications for gas storage applications. By correlating the structural features of the MOFs with their gas adsorption performance, the research aims to provide valuable insights into the design principles for developing high-performance MOFs for gas storage applications. In conclusion, the project seeks to contribute to the advancement of MOF research by developing novel materials tailored for efficient gas storage applications. The synthesis and characterization of these MOFs are expected to provide new insights into the design of porous materials with enhanced gas adsorption properties, paving the way for the development of sustainable energy storage solutions.